关键词:
borylation
C—H functionalization
silylation
trans-effect
X-type silyl ligand
σ-donating characteristic
摘要:
The development of novel ligands for transition-metal (TM) catalysis holds significant importance. With the rapid evolution of organosilicon chemistry, summarizing the topic of X-type silyl ligands for TM catalysis is appealing and timely. The unique σ-donating characteristics and trans-effects of silyl ligands are explored, and their pivotal role in enhancing the reactivity and selectivity of C—H functionalization reactions is elucidated. Furthermore, valuable insights into future advancements in this field are also prospected, with the goal of inspiring new applications and perspectives in the realm of catalytic synthetic chemistry. © 2025 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.